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Its enzymatic function is based on two aspects: its catalytic activity and the auto- S -glutathionylation of GSTπ by itself on Cys47 and Cys10, both of which disturb the subsequent interaction with c-Jun NH 2 -terminal kinase (JNK), resulting in the formation of a GSTπ multimer 30 (Figure 3)

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This leads to the release and subsequent cytoplasmic translocation of p53, which in turn activates a transcription-independent pro-apoptotic pathway, facilitating the selective clearance of senescent cells (Kong et al., 2025